Update Readme to add missing syntax highlighting
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Description
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NOTE: All patches should be made against master, not a maintenance branch like 3.1, 2.5, etc. That is unless the bug is already fixed in master, but not in that version series.
If it fixes a bug or resolves a feature request, be sure to link to that issue via (Fixes #4412) for example.
I noticed the code block in the Simple example didn't have syntax highlighting, so I made a small MR. Sorry if this was an intentional choice.
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